Title
Exit wave reconstruction from focal series of HRTEM images, single crystal XRD and total energy studies on <tex>$Sb_{x}WO_{3+y}$</tex> (<tex>$x\sim0.11$</tex>) Exit wave reconstruction from focal series of HRTEM images, single crystal XRD and total energy studies on <tex>$Sb_{x}WO_{3+y}$</tex> (<tex>$x\sim0.11$</tex>)
Author
Faculty/Department
Faculty of Sciences. Physics
Publication type
article
Publication
München ,
Subject
Physics
Chemistry
Source (journal)
Zeitschrift für Kristallographie. - München
Volume/pages
227(2012) :6 , p. 341-349
ISSN
0044-2968
ISI
000307314200003
Carrier
E
Target language
English (eng)
Full text (Publishers DOI)
Affiliation
University of Antwerp
Abstract
A new tungsten bronze in the SbWO system has been prepared in a solid state reaction from Sb2O3, WO3 and W metal powder. The average structure was determined by single crystal X-ray diffraction. SbxWO3+y (x ∼ 0.11) crystallizes in the orthorhombic space group Pm21n (no. 31), a = 27.8135(9) Å, b = 7.3659(2) Å and c = 3.8672(1) Å. The structure belongs to the (n)-ITB class of intergrowth tungsten bronzes. It contains slabs of hexagonal channels formed by six WO6 octahedra. These slabs are separated by three layers of WO6 octahedra that are arranged in a WO3-type fashion. The WO6 octahedra share all vertices to build up a three-dimensional framework. The hexagonal channels are filled with Sb atoms to ∼80% and additional O atoms. The atoms are shifted out of the center of the channels. Exit-wave reconstruction of focal series of high resolution-transmission-electron-microscope (HRTEM) images combined with statistical paramäeter estimation techniques allowed to study local ordering in the channels. Sb atoms in neighbouring channels tend to be displaced in the same direction, which is in agreement with total energy calculations on ordered structure models, but the ratio of the occupation of the two possible Sb sites varies from channel to channel. The structure of SbxWO3+y exhibits pronounced local modulations.
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Full text (open access)
https://repository.uantwerpen.be/docman/irua/5d6d47/101218.pdf
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