Title
Is their potential for post-synthetic brominating reactions on benzene bridged PMOs? Is their potential for post-synthetic brominating reactions on benzene bridged PMOs?
Author
Faculty/Department
Faculty of Sciences. Chemistry
Publication type
article
Publication
Amsterdam ,
Subject
Physics
Chemistry
Engineering sciences. Technology
Source (journal)
Microporous and mesoporous materials: zeolites, clays, carbons and related materials. - Amsterdam
Volume/pages
164(2012) , p. 49-55
ISSN
1387-1811
ISI
000310770100008
Carrier
E
Target language
English (eng)
Full text (Publishers DOI)
Affiliation
University of Antwerp
Abstract
Benzene bridged PMOs show only little applicability towards catalysis, sorption, scavenging, etc. Nevertheless organic synthesis supplies a wide range of possible modification reactions on aromatic groups. One of these is brominating benzene bridged PMOs, hereby following the successful approach of the as-synthesized UKON materials of brominated benzene bridged PMOs. In this study however, for the first time different post-modification reactions were examined for brominating the benzene rings. The synthesized materials were thoroughly tested and evaluated accordingly and specifically emphasis was put on occurring structural changes. The results show that the principles of organic chemistry are not so straightforwardly transferred to nanoporous material science.
E-info
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