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Title
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Synthesis, crystal structure, and properties of -type
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Author
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Abstract
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| Single crystals of Bi3Mn1.9Te1.1O11 were prepared from NaCl+KCl flux. This compound adopts KSbO3-type crystal structure as evidenced by electron and single crystal X-ray diffraction analysis. The three-dimensional channel structure is formed by corner-sharing octahedral (Mn0.63Te0.37)2O10 dimers and two identical (Bi1)4(Bi2)2 interpenetrating lattices. The intra-dimer Mn/TeMn/Te distances in Bi3Mn1.9Te1.1O11 are short and are consistent with weak metalmetal interactions. The mixed oxidation state of manganese and the edge-sharing octahedral features are confirmed by X-ray near edge absorption spectroscopy measurements, which indicate Bi3(MnIII1.1MnIV0.8)TeVI1.1O11 with 57.7% Mn3+ and 42.3% Mn4+. The partial substitution of Te for Mn perturbs long-range magnetic interactions, thereby destroying the ferromagnetic ordering found in Bi3Mn3O11 (TC=150 K). |
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Language
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English
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Source (journal)
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Journal of solid state chemistry. - London
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Publication
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London
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2013
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ISSN
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0022-4596
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DOI
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10.1016/J.JSSC.2012.07.038
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Volume/pages
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197
(2013)
, p. 543-549
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ISI
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000312281000076
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Full text (Publisher's DOI)
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Full text (publisher's version - intranet only)
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