Title
<tex>$KSm(MoO_{4})_{2}$</tex>, an incommensurately modulated and partially disordered scheelite-like structure <tex>$KSm(MoO_{4})_{2}$</tex>, an incommensurately modulated and partially disordered scheelite-like structure
Author
Faculty/Department
Faculty of Sciences. Physics
Publication type
article
Publication
Copenhagen ,
Subject
Chemistry
Source (journal)
Acta crystallographica: section B: structural science. - Copenhagen
Volume/pages
64(2008) :Part 2 , p. 160-171
ISSN
0108-7681
ISI
000253992600004
Carrier
E
Target language
English (eng)
Full text (Publishers DOI)
Affiliation
University of Antwerp
Abstract
The incommensurately modulated scheelite-like KSm( MoO4)(2) structure has been refined in the monoclinic superspace group I2/b(alpha beta 0)00 by the Rietveld method on the basis of synchrotron radiation powder diffraction data. The systematic broadening of satellite reflections has been accounted for by applying anisotropic microstrain line-broadening. The microstructure has been studied by transmission electron microscopy (TEM). The partial disorder of the K and Sm cations in the A position is best approximated by a combination of harmonic and complex crenel functions with (0.952Sm + 0.048K) and (0.952K + 0.048Sm) atomic domains. This combination yields a compositional wave distribution from {KMoO4} to {SmMoO4} observed in the ab structure projection along q. The specific features of KSm(MoO4)(2) and degree of the A-cation ordering are discussed in comparison with the previously reported structure of KNd(MoO4)(2).
E-info
https://repository.uantwerpen.be/docman/iruaauth/f83fc8/3694434.pdf
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