Title
Synthesis and spectroscopic characterization of the heterobimetallic chain compounds <tex>$[MPdL_{2}]_{n}$</tex> and <tex>$[CuPtL_{2}]_{n}$</tex> (M = Co, Ni, Cu, Zn, Pt; <tex>$L^{2-}$</tex> = N,N'-dimethylmonothiooxamido) Synthesis and spectroscopic characterization of the heterobimetallic chain compounds <tex>$[MPdL_{2}]_{n}$</tex> and <tex>$[CuPtL_{2}]_{n}$</tex> (M = Co, Ni, Cu, Zn, Pt; <tex>$L^{2-}$</tex> = N,N'-dimethylmonothiooxamido)
Author
Faculty/Department
Faculty of Sciences. Chemistry
Publication type
article
Publication
New York ,
Subject
Chemistry
Source (journal)
Spectroscopy letters. - New York
Volume/pages
26(1993) :5 , p. 777-791
ISSN
0038-7010
ISI
A1993LD54700005
Carrier
E
Target language
English (eng)
Full text (Publishers DOI)
Affiliation
University of Antwerp
Abstract
By using the ''complexes as ligands'' synthetic strategy and the unique [Pd(LH)2] and [Pt(LH)2] precursors, the novel heterobimetallic polymeric compounds [MPdL2]n and [CuPtL2]n (M = Co, Ni, Cu, Zn, Pt; L2- = the dianion of N,N'-dimethylmonothiooxamide) have been prepared. The vibrational analysis of the complexes is given using various isotopic substitutions. The polymers consist of alternate planar PdO2S2 (or PtO2S2) and tetrahedrally-distorted planar MN4 structural units.
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