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Synthesis and spectroscopic characterization of the heterobimetallic chain compounds and (M = Co, Ni, Cu, Zn, Pt; = N,N'-dimethylmonothiooxamido)
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| Abstract |
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| By using the ''complexes as ligands'' synthetic strategy and the unique [Pd(LH)2] and [Pt(LH)2] precursors, the novel heterobimetallic polymeric compounds [MPdL2]n and [CuPtL2]n (M = Co, Ni, Cu, Zn, Pt; L2- = the dianion of N,N'-dimethylmonothiooxamide) have been prepared. The vibrational analysis of the complexes is given using various isotopic substitutions. The polymers consist of alternate planar PdO2S2 (or PtO2S2) and tetrahedrally-distorted planar MN4 structural units. | | |
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English
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| Source (journal) |
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Spectroscopy letters. - New York | |
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New York : 1993
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0038-7010
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26:5(1993), p. 777-791
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A1993LD54700005
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