Publication
Title
Synthesis of stable sulfines by oxidation of chlorodithioformates
Author
Abstract
The oxidation of chlorodithioformates with in-chloroperoxybenzoic acid in dichloromethane at room temperature provides an efficient stereoselective synthesis of (Z)-sulfines. The expected (Z)-configuration was confirmed by an X-ray structure determination. The sulfines are reactive dienophiles and react with 2,3-dimethyl-1,3-butadiene to give the corresponding dihydrothiopyran-S-oxide.
Language
English
Source (journal)
Monatshefte für Chemie. - Wien
Publication
Wien : 2004
ISSN
0026-9247
Volume/pages
135:7(2004), p. 879-884
ISI
000222607900015
Full text (Publisher's DOI)
Full text (publisher's version - intranet only)
UAntwerpen
Publication type
Subject
External links
Web of Science
Record
Identification
Creation 03.01.2013
Last edited 08.08.2017