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Title
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Synthesis of stable sulfines by oxidation of chlorodithioformates
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Author
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Abstract
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| The oxidation of chlorodithioformates with in-chloroperoxybenzoic acid in dichloromethane at room temperature provides an efficient stereoselective synthesis of (Z)-sulfines. The expected (Z)-configuration was confirmed by an X-ray structure determination. The sulfines are reactive dienophiles and react with 2,3-dimethyl-1,3-butadiene to give the corresponding dihydrothiopyran-S-oxide. |
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Language
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English
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Source (journal)
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Monatshefte für Chemie. - Wien
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Publication
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Wien
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2004
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ISSN
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0026-9247
[print]
1434-4475
[online]
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Volume/pages
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135
:7
(2004)
, p. 879-884
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ISI
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000222607900015
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Full text (Publisher's DOI)
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Full text (publisher's version - intranet only)
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