Title
Synthesis of stable sulfines by oxidation of chlorodithioformates Synthesis of stable sulfines by oxidation of chlorodithioformates
Author
Publication type
article
Publication
Wien ,
Subject
Chemistry
Source (journal)
Monatshefte für Chemie. - Wien
Volume/pages
135(2004) :7 , p. 879-884
ISSN
0026-9247
ISI
000222607900015
Carrier
E
Target language
English (eng)
Full text (Publishers DOI)
Abstract
The oxidation of chlorodithioformates with in-chloroperoxybenzoic acid in dichloromethane at room temperature provides an efficient stereoselective synthesis of (Z)-sulfines. The expected (Z)-configuration was confirmed by an X-ray structure determination. The sulfines are reactive dienophiles and react with 2,3-dimethyl-1,3-butadiene to give the corresponding dihydrothiopyran-S-oxide.
E-info
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