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Synthesis of stable sulfines by oxidation of chlorodithioformates
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| Abstract |
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| The oxidation of chlorodithioformates with in-chloroperoxybenzoic acid in dichloromethane at room temperature provides an efficient stereoselective synthesis of (Z)-sulfines. The expected (Z)-configuration was confirmed by an X-ray structure determination. The sulfines are reactive dienophiles and react with 2,3-dimethyl-1,3-butadiene to give the corresponding dihydrothiopyran-S-oxide. | |
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English
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| Source (journal) |
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Monatshefte für Chemie. - Wien |
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Wien : 2004
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| ISSN |
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0026-9247
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| Volume/pages |
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135:7(2004), p. 879-884
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| ISI |
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000222607900015
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| Full text (publisher's version - intranet only) |
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