|
Title
|
|
|
|
Synthesis of stable sulfines by oxidation of chlorodithioformates
|
|
|
Author
|
|
|
|
|
|
|
Abstract
|
|
|
|
| The oxidation of chlorodithioformates with in-chloroperoxybenzoic acid in dichloromethane at room temperature provides an efficient stereoselective synthesis of (Z)-sulfines. The expected (Z)-configuration was confirmed by an X-ray structure determination. The sulfines are reactive dienophiles and react with 2,3-dimethyl-1,3-butadiene to give the corresponding dihydrothiopyran-S-oxide. |
|
|
|
Language
|
|
|
|
English
|
|
|
Source (journal)
|
|
|
|
Monatshefte für Chemie. - Wien
|
|
|
Publication
|
|
|
|
Wien
:
2004
|
|
|
ISSN
|
|
|
|
0026-9247
[print]
1434-4475
[online]
|
|
|
DOI
|
|
|
|
10.1007/S00706-004-0165-Y
|
|
|
Volume/pages
|
|
|
|
135
:7
(2004)
, p. 879-884
|
|
|
ISI
|
|
|
|
000222607900015
|
|
|
Full text (Publisher's DOI)
|
|
|
|
|
|
|
Full text (publisher's version - intranet only)
|
|
|
|
|
|