Title
Regularities in melting points of lithium halides: Is LiH anomalous? Regularities in melting points of lithium halides: Is LiH anomalous?
Author
Publication type
article
Publication
London ,
Subject
Physics
Chemistry
Source (journal)
Physics and chemistry of liquids. - London
Volume/pages
41(2003) :3 , p. 303-308
ISSN
0031-9104
ISI
000183466800008
Carrier
E
Target language
English (eng)
Full text (Publishers DOI)
Affiliation
University of Antwerp
Abstract
Using experimental data for the melting temperature T-m for four Li halides (F to I), it is demonstrated that T(m)Z(1/3) is close to constant, congruent to (2530 +/- 250) K, where Z is the atomic number of the halogen. This formula is not appropriate for what sometimes is considered the simplest halide, LiH, and therefore alternatives are investigated which involve a characteristic electrostatic energy e(2)/epsilons with s the internuclear separation and epsilon the static dielectric constant.
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