Publication
Title
Isoquinoline alkaloids : NMR and x-ray study. Part 2
Author
Abstract
Continuing our systematic N-15 NMR study of isoquinoline alkaloids, we report a contribution extending our previous paper. The N-15 NMR chemical shifts and N-15,H-1 long-range coupling pathways of tertiary and quaternary isoquinoline alkaloids of several constitutional types are presented. The selected compounds belong to the protoberberine, proaporphine, pavinane, rhoeadine and phtalideisoquinoline classes of alkaloids and were investigated by gradient-selected inverse-detected multiple bond correlation experiments (GHMBC and GSQMBC). In addition, x-ray data and the principal geometric parameters of stylopine, mecambridine, norchelerythrine, isothebaine and mecambrine are reported and discussed. Copyright (C) 2002 John Wiley Sons, Ltd.
Language
English
Source (journal)
Magnetic resonance in chemistry. - Chichester
Publication
Chichester : 2002
ISSN
0749-1581
Volume/pages
40:11(2002), p. 687-692
ISI
000178816300002
Full text (Publisher's DOI)
Full text (publisher's version - intranet only)
UAntwerpen
Faculty/Department
Research group
Publication type
Subject
Affiliation
Publications with a UAntwerp address
External links
Web of Science
Record
Identification
Creation 03.01.2013
Last edited 23.06.2017
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