Title
Comparative study of the metal-ligand bond strength in <tex>$Mn^{II}/X/U$</tex> complexes (X = Cl, Br, I; U = urea)
Author
Faculty/Department
Faculty of Applied Economics
Faculty of Sciences. Chemistry
Publication type
article
Publication
Amsterdam ,
Subject
Chemistry
Source (journal)
Journal of molecular structure. - Amsterdam
Volume/pages
525(2000) , p. 173-183
ISSN
0022-2860
ISI
000087786900017
Carrier
E
Target language
English (eng)
Full text (Publishers DOI)
Affiliation
University of Antwerp
Abstract
The synthesis, structure, vibrational analysis and a comparative vibrational study in function of the structure and the metal-ligand bond strength are discussed for a series of Mn(II)-urea-halogenide complexes. Complex [MnCl2U] has been prepared and studied fur the first time. The single-crystal X-ray structure of the 1:6-bromide complex reveals the presence of octahedral [MnU6](2+) ions and bromide counterions. (C) 2000 Elsevier Science Ltd. All rights reserved.
E-info
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Handle