Title
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Differential equation for ground-state electron density of He-like ions for large atomic number
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Author
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Abstract
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An explicit differential equation satisfied by the ground-state electron density of He-like ions is constructed for large atomic number Z, As in the authors' earlier work on the Hookean atom, the result is a linear third-order homogeneous differential equation. The first-order interacting density matrix is then written in terms of the ground-state electron density. A functional for the correlation kinetic energy is thereby exhibited in the large Z Limit for these two-electron ions. (C) 1999 Elsevier Science B.V. All rights reserved. |
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Language
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English
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Source (journal)
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Chemical physics letters. - Amsterdam, 1967, currens
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Publication
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Amsterdam
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1999
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ISSN
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0009-2614
[print]
1873-4448
[online]
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DOI
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10.1016/S0009-2614(99)00384-X
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Volume/pages
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305
:5-6
(1999)
, p. 429-432
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ISI
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000080630800020
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Full text (Publisher's DOI)
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Full text (publisher's version - intranet only)
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