Title
Orientation of the isopropyl grouping in isopropyl chloroformate and isopropyl cyanoformate Orientation of the isopropyl grouping in isopropyl chloroformate and isopropyl cyanoformate
Author
Faculty/Department
Faculty of Sciences. Chemistry
Publication type
article
Publication
Amsterdam ,
Subject
Chemistry
Source (journal)
Journal of molecular structure. - Amsterdam
Volume/pages
328(1994) , p. 211-220
ISSN
0022-2860
ISI
A1994PV81300017
Carrier
E
Target language
English (eng)
Full text (Publishers DOI)
Affiliation
University of Antwerp
Abstract
The vapour phase infrared contours of the carbonyl stretching of five differently deuterated derivatives of isopropyl chloroformate, and of three differently deuterated derivatives of isopropyl cyanoformate have been investigated. Simulations using rigid asymmetric top calculations of the observed contours indicate that the COCH dihedral angle is close to 20 degrees in both the chloroformate and the cyanoformate ester.
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