| Title |
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Orientation of the isopropyl grouping in isopropyl chloroformate and isopropyl cyanoformate
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| Author |
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| Abstract |
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| The vapour phase infrared contours of the carbonyl stretching of five differently deuterated derivatives of isopropyl chloroformate, and of three differently deuterated derivatives of isopropyl cyanoformate have been investigated. Simulations using rigid asymmetric top calculations of the observed contours indicate that the COCH dihedral angle is close to 20 degrees in both the chloroformate and the cyanoformate ester. | |
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| Language |
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English
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| Source (journal) |
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Journal of molecular structure. - Amsterdam |
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| Publication |
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Amsterdam : 1994
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| ISSN |
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0022-2860
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| Volume/pages |
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328(1994), p. 211-220
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| ISI |
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A1994PV81300017
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| Full text (publisher's version - intranet only) |
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