Publication
Title
Lewis acid promoted Mannich type reactions of , -dichloro aldimines with potassium organotrifluoroborates
Author
Abstract
Potassium phenylethynyltrifluoroborate and potassium styryltrifluoroborates react with alpha, alpha-dichlorinated aldimines in the presence of BF(3). OEt(2) as a Lewis acid to give a new stable class of functionalized propargylamines and allylamines. The use of hexafluoroisopropanol as a co-solvent in this modified Petasis reaction allows high yield isolation of the target compounds. (C) 2007 Elsevier Ltd. All rights reserved.
Language
English
Source (journal)
Tetrahedron. - Oxford
Publication
Oxford : 2007
ISSN
0040-4020
Volume/pages
63:36(2007), p. 8921-8931
ISI
000252091700028
Full text (Publishers DOI)
Full text (publishers version - intranet only)
UAntwerpen
Faculty/Department
Publication type
Subject
External links
Web of Science
Record
Identification
Creation 28.01.2013
Last edited 19.04.2017