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Novel boronic acid Mannich reactions of ,-dichloro- and ,,-trichloroaldehydes with arylboronic acids
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| Abstract |
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| A novel variation of the boronic acid Mannich (BAM) reaction is described, in which alpha,alpha-dichloro- and alpha,alpha,omega-trichloroaldehydes, morpholine, and arylboronic acids are used. During this one-pot reaction in refluxing toluene, 1-phenyl-1-morpholinoalkan-2-ones form in moderate yields. The dichloromethylene group is formally converted into a ketone functionality and as such acts as a masked carbonyl group. | | |
| Language |
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English
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| Source (journal) |
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Synthesis : journal of synthetic organic chemistry. - Stuttgart, 1969, currens | |
| Publication |
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Stuttgart : Thieme, 2007
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| ISSN |
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0039-7881 [print]
1437-210X [online]
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| Volume/pages |
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3(2007), p. 433-441
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| ISI |
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000244299300016
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