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Title
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Novel boronic acid Mannich reactions of ,-dichloro- and ,,-trichloroaldehydes with arylboronic acids
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Author
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Abstract
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| A novel variation of the boronic acid Mannich (BAM) reaction is described, in which alpha,alpha-dichloro- and alpha,alpha,omega-trichloroaldehydes, morpholine, and arylboronic acids are used. During this one-pot reaction in refluxing toluene, 1-phenyl-1-morpholinoalkan-2-ones form in moderate yields. The dichloromethylene group is formally converted into a ketone functionality and as such acts as a masked carbonyl group. |
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Language
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English
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Source (journal)
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Synthesis : journal of synthetic organic chemistry. - Stuttgart, 1969, currens
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Publication
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Stuttgart
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Thieme
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2007
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ISSN
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0039-7881
[print]
1437-210X
[online]
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DOI
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10.1055/S-2007-965880
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Volume/pages
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3
(2007)
, p. 433-441
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ISI
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000244299300016
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Full text (Publisher's DOI)
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