|
Title
|
|
|
|
Novel boronic acid Mannich reactions of ,-dichloro- and ,,-trichloroaldehydes with arylboronic acids
| |
|
Author
|
|
|
|
| |
|
Abstract
|
|
|
|
| A novel variation of the boronic acid Mannich (BAM) reaction is described, in which alpha,alpha-dichloro- and alpha,alpha,omega-trichloroaldehydes, morpholine, and arylboronic acids are used. During this one-pot reaction in refluxing toluene, 1-phenyl-1-morpholinoalkan-2-ones form in moderate yields. The dichloromethylene group is formally converted into a ketone functionality and as such acts as a masked carbonyl group. |
| |
|
Language
|
|
|
|
English
| |
|
Source (journal)
|
|
|
|
Synthesis : journal of synthetic organic chemistry. - Stuttgart, 1969, currens
| |
|
Publication
|
|
|
|
Stuttgart
:
Thieme
,
2007
| |
|
ISSN
|
|
|
|
0039-7881
[print]
1437-210X
[online]
| |
|
Volume/pages
|
|
|
|
3
(2007)
, p. 433-441
| |
|
ISI
|
|
|
|
000244299300016
| |
|
Full text (Publisher's DOI)
|
|
|
|
| |
|