Title
Grob-type fragmentation of N-alkyl-2-cyano-5-bromopiperidines to unsaturated imidoyl cyanides Grob-type fragmentation of N-alkyl-2-cyano-5-bromopiperidines to unsaturated imidoyl cyanides
Author
Faculty/Department
Faculty of Sciences. Chemistry
Publication type
article
Publication
Oxford ,
Subject
Chemistry
Source (journal)
Tetrahedron letters. - Oxford
Volume/pages
42(2001) :23 , p. 3921-3923
ISSN
0040-4039
ISI
000168959100039
Carrier
E
Target language
English (eng)
Abstract
2-Cyano-5-bromopiperidines. derived from the stereoselective addition of cyanide to 5-bromomethyl-l-pyrrolinium salts, underwent a Grob fragmentation by reaction with sodium hydride in dimethylformamide, affording unsaturated imidoyl cyanides. (C) 2001 Elsevier Science Ltd. All rights reserved.
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