Publication
Title
Synthesis of 2-acyl-3-chloropyrroles : application to the synthesis of the trail pheromone of the ant **Atta texana**
Author
Abstract
Alkyl 3-chloropyrrole-2-carboxylates and 2-alkanoyl-3-chloropyrroles are conveniently prepared from 2-alkyl-1-pyrrolines by tetra- and pentahalogenation with N-chlorosuccinimide, subsequent base-induced aromatisation with sodium alkoxides in the corresponding alcohol and final acid hydrolysis of the resulting orthoester or acetal functions into the 3-chloropyrrole. The developed strategy is applied to the synthesis of the trail pheromone of the ant Atta texnna. (C) 1999 Elsevier Science Ltd. All rights reserved.
Language
English
Source (journal)
Tetrahedron. - Oxford
Publication
Oxford : 1999
ISSN
0040-4020
Volume/pages
55:13(1999), p. 4133-4152
ISI
000079403800029
UAntwerpen
Faculty/Department
Publication type
Subject
External links
Web of Science
Record
Identification
Creation 28.01.2013
Last edited 08.10.2017