Title
A convenient synthesis of 3-functionalized 5-alkoxymethyl- and 5-phenoxymethyl-2(5H)-furanones and their transformations into related epoxy and methylene lactones
Author
Faculty/Department
Faculty of Sciences. Chemistry
Publication type
article
Publication
Oxford ,
Subject
Chemistry
Source (journal)
Tetrahedron. - Oxford
Volume/pages
54(1998) :9 , p. 1801-1808
ISSN
0040-4020
ISI
000071895500012
Carrier
E
Target language
English (eng)
Full text (Publishers DOI)
Abstract
A convenient procedure for the preparation of 3-functionalized 5-alkoxymethyl- and 5-phenoxymethyl-2(5H)-furanones is described. The method is based on the condensation of various beta-alkoxy- or beta-phenoxy-alpha-hydroxy ketones with beta-activated esters in the presence of catalytic amounts of sodium methoxide. Results are reported showing the possible transformations of these 2(5H)-furanones into related epoxy and alpha-methylene lactones. (C) 1998 Elsevier Science Ltd. All rights reserved.
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