Publication
Title
Enantio- and diastereoselective palladium catalysed arylative and vinylative allene carbocyclisation cascades
Author
Abstract
The enantioselective synthesis of heavily decorated spirolactams has been accomplished via an arylative or vinylative allene carbocyclisation cascade. Mediated by silver phosphate, a range of allene-linked pro-nucleophiles and aryl or vinyl iodides were reacted in the presence of catalytic Pd(OAc)(2) and chiral bis-(oxazoline) ligands to afford the spirolactam products in good yields and high enantio-and diastereoselectivities.
Language
English
Source (journal)
ChemComm / Royal Society of Chemistry [London] - London, 1996, currens
Publication
London : 2013
ISSN
1359-7345 [print]
1364-548X [online]
Volume/pages
49:46(2013), p. 5265-5267
ISI
000318917900006
Full text (Publisher's DOI)
Full text (publisher's version - intranet only)
UAntwerpen
Faculty/Department
Research group
[E?say:metaLocaldata.cgzprojectinf]
Publication type
Subject
Affiliation
Publications with a UAntwerp address
External links
Web of Science
Record
Identification
Creation 19.07.2013
Last edited 05.08.2017
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