Publication
Title
Extraction of a quantitative reaction mechanism from linear sweep voltammograms obtained on a rotating disk electrode
Author
Abstract
A new methodology to quantitatively determine the mass and charge transfer parameters of an electrochemical reaction is applied successfully in this work for the study of the reduction of ferricyanide to ferrocyanide at a platinum electrode, rotating at 1000 rpm. It is concluded that the reaction can be described by a simple electron transfer and the values of the charge transfer parameters are: alpha(ox)= 5.00E-01 +/- 8.75E-03, k(ox) = 1.39E-08 +/- 2.28E-09 and k(red) = 1.25E+00 +/- 2.01E-01.
Language
English
Source (journal)
WIT Transactions on the engineering sciences -Simulation of Electrochemical Processes II
Publication
2007
Volume/pages
54(2007), p. 173-182
ISI
000248252400017
Full text (Publisher's DOI)
UAntwerpen
Faculty/Department
Publication type
Subject
External links
Web of Science
Record
Identification
Creation 20.09.2013
Last edited 19.07.2017