Publication
Title
Effect of lone-electron-pair cations on the orientation of crystallographic shear planes in anion-deficient perovskites
Author
Abstract
Factors affecting the structure and orientation of the crystallographic shear (CS) planes in anion-deficient perovskites are investigated using the (Pb1−zSrz)1−xFe1+xO3−y perovskites as a model system. The orientation of the CS planes in the system varies unevenly with z. A comparison of the structures with different CS planes revels that the orientation of the CS planes is governed mainly by the stereochemical activity of the lone-electron-pair cations inside the perovskite blocks.
Language
English
Source (journal)
Inorganic chemistry / American Chemical Society. - Easton, Pa
Publication
Easton, Pa : 2013
ISSN
0020-1669
Volume/pages
52:17(2013), p. 10009-10020
ISI
000326129000037
Full text (Publisher's DOI)
UAntwerpen
Faculty/Department
Research group
Publication type
Subject
Affiliation
Publications with a UAntwerp address
External links
Web of Science
Record
Identification
Creation 19.11.2013
Last edited 03.07.2017
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