Title
Effect of lone-electron-pair cations on the orientation of crystallographic shear planes in anion-deficient perovskites Effect of lone-electron-pair cations on the orientation of crystallographic shear planes in anion-deficient perovskites
Author
Faculty/Department
Faculty of Sciences. Physics
Publication type
article
Publication
Easton, Pa ,
Subject
Physics
Chemistry
Source (journal)
Inorganic chemistry / American Chemical Society. - Easton, Pa
Volume/pages
52(2013) :17 , p. 10009-10020
ISSN
0020-1669
ISI
000326129000037
Carrier
E
Target language
English (eng)
Full text (Publishers DOI)
Affiliation
University of Antwerp
Abstract
Factors affecting the structure and orientation of the crystallographic shear (CS) planes in anion-deficient perovskites are investigated using the (Pb1−zSrz)1−xFe1+xO3−y perovskites as a model system. The orientation of the CS planes in the system varies unevenly with z. A comparison of the structures with different CS planes revels that the orientation of the CS planes is governed mainly by the stereochemical activity of the lone-electron-pair cations inside the perovskite blocks.
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