Title
Comparative study of measured and computed Raman optical activity of a chiral transition metal complex Comparative study of measured and computed Raman optical activity of a chiral transition metal complex
Author
Faculty/Department
Faculty of Sciences. Chemistry
Publication type
article
Publication
Weinheim ,
Subject
Physics
Chemistry
Source (journal)
ChemPhysChem: a European journal of chemical physics and physical chemistry. - Weinheim
Volume/pages
12(2011) :8 , p. 1419-1421
ISSN
1439-4235
ISI
000290865800002
Carrier
E
Target language
English (eng)
Full text (Publishers DOI)
Abstract
On the ROA to somewhere: The first combined study of measured and computed Raman optical activity (ROA) of a transition metal complex under non-resonant scattering conditions is reported. ROA measurements of the two enantiomers of the dichloro[ethylenebis(4,5,6,7-tetrahydro-1-indenyl)] zirconium(IV) complex yield virtually mirror-image ROA spectra. The experimental spectra are directly comparable with predicted ROA spectra.
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