Publication
Title
Determination of the helical screw sense and side-group chirality of a synthetic chiral polymer from Raman optical activity
Author
Abstract
Splitting it up: Excellent agreement between the experimental and the quantum-chemically simulated Raman optical activity (ROA) spectrum of (+)-poly(trityl methacrylate) shows that the polymer backbone adopts a left-handed helical conformation while the trityl side groups display a left-handed propeller conformation. Thus ROA can be used to determine the complete structure of synthetic chiral polymers in solution.
Language
English
Source (journal)
Angewandte Chemie: international edition in English. - Weinheim
Publication
Weinheim : 2011
ISSN
1433-7851
0570-0833
Volume/pages
50:42(2011), p. 9973-9976
ISI
000296207100039
Full text (Publisher's DOI)
Full text (publisher's version - intranet only)
UAntwerpen
Faculty/Department
Publication type
Subject
External links
Web of Science
Record
Identification
Creation 20.12.2013
Last edited 08.08.2017