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Title
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Determination of the helical screw sense and side-group chirality of a synthetic chiral polymer from Raman optical activity
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Author
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Abstract
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| Splitting it up: Excellent agreement between the experimental and the quantum-chemically simulated Raman optical activity (ROA) spectrum of (+)-poly(trityl methacrylate) shows that the polymer backbone adopts a left-handed helical conformation while the trityl side groups display a left-handed propeller conformation. Thus ROA can be used to determine the complete structure of synthetic chiral polymers in solution. |
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Language
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English
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Source (journal)
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Angewandte Chemie: international edition in English. - Weinheim
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Publication
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Weinheim
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2011
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ISSN
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1433-7851
0570-0833
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DOI
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10.1002/ANIE.201104345
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Volume/pages
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50
:42
(2011)
, p. 9973-9976
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ISI
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000296207100039
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Full text (Publisher's DOI)
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Full text (publisher's version - intranet only)
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