Title
Formation and thermal stability of Au-<tex>$SiO_{2}$</tex> nanohybrids : insight into the mechanism and morphology by electron tomography Formation and thermal stability of Au-<tex>$SiO_{2}$</tex> nanohybrids : insight into the mechanism and morphology by electron tomography
Author
Faculty/Department
Faculty of Sciences. Physics
Publication type
article
Publication
Weinheim ,
Subject
Chemistry
Source (journal)
Angewandte Chemie: international edition in English. - Weinheim
Volume/pages
53(2014) :15 , p. 3970-3974
ISSN
1433-7851
1433-7851
0570-0833
ISI
000333634800036
Carrier
E
Target language
English (eng)
Full text (Publishers DOI)
Affiliation
University of Antwerp
Abstract
Gold-silica hybrids are appealing in different fields of applications like catalysis, sensorics, drug delivery, and biotechnology. In most cases, the morphology and distribution of the heterounits play significant roles in their functional behavior. Methods of synthesizing these hybrids, with variable ordering of the heterounits, are replete; however, a complete characterization in three dimensions could not be achieved yet. A simple route to the synthesis of Au-decorated SiO2 spheres is demonstrated and a study on the 3D ordering of the heterounits by scanning transmission electron microscopy (STEM) tomography is presentedat the final stage, intermediate stages of formation, and after heating the hybrid. The final hybrid evolves from a soft self-assembled structure of Au nanoparticles. The hybrid shows good thermal stability up to 400 degrees C, beyond which the Au particles start migrating inside the SiO2 matrix. This study provides an insight in the formation mechanism and thermal stability of the structures which are crucial factors for designing and applying such hybrids in fields of catalysis and biotechnology. As the method is general, it can be applied to make similar hybrids based on SiO2 by tuning the reaction chemistry as needed.
E-info
https://repository.uantwerpen.be/docman/iruaauth/f68630/9507576.pdf
http://ematweb.uantwerpen.be/emat/postprints/2019pp.pdf
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Full text (open access)
https://repository.uantwerpen.be/docman/irua/b094c4/117186.pdf
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