Title
Axially chiral BODIPYs Axially chiral BODIPYs
Author
Faculty/Department
Faculty of Sciences. Chemistry
Publication type
article
Publication
London ,
Subject
Chemistry
Source (journal)
ChemComm. - London, 1996, currens
Volume/pages
50(2014) :36 , p. 4714-4716
ISSN
1359-7345
ISI
000334601000014
Carrier
E
Target language
English (eng)
Full text (Publishers DOI)
Affiliation
University of Antwerp
Abstract
The synthesis and resolution of a class of chiral organic fluorophores, axially chiral 4,4-difluoro-4-bora-3a,4a-diaza-s-indacenes (Ax*-BODIPY), is described. Ax*-BODIPYs were prepared through a modular synthesis combined with a late stage Heck functionalisation. Resolution was achieved by preparative chiral HPLC. Absolute stereochemical assignment was performed by comparison of experimental ECD spectra with TD-DFT calculations.
Full text (open access)
https://repository.uantwerpen.be/docman/irua/6f64cd/7638.pdf
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