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Title
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Axially chiral BODIPYs
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Author
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Abstract
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| The synthesis and resolution of a class of chiral organic fluorophores, axially chiral 4,4-difluoro-4-bora-3a,4a-diaza-s-indacenes (Ax*-BODIPY), is described. Ax*-BODIPYs were prepared through a modular synthesis combined with a late stage Heck functionalisation. Resolution was achieved by preparative chiral HPLC. Absolute stereochemical assignment was performed by comparison of experimental ECD spectra with TD-DFT calculations. |
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Language
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English
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Source (journal)
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Chemical communications / Royal Society of Chemistry [London] - London, 1996, currens
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Publication
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London
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Royal Society of Chemistry
,
2014
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ISSN
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1359-7345
[print]
1364-548X
[online]
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DOI
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10.1039/C4CC00851K
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Volume/pages
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50
:36
(2014)
, p. 4714-4716
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ISI
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000334601000014
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Full text (Publisher's DOI)
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Full text (open access)
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