Title
<tex>$Au_{2}S_{x}/CdS$</tex> nanorods by cation exchange : mechanistic insights into the competition between cation-exchange and metal ion reduction <tex>$Au_{2}S_{x}/CdS$</tex> nanorods by cation exchange : mechanistic insights into the competition between cation-exchange and metal ion reduction
Author
Faculty/Department
Faculty of Sciences. Physics
Publication type
article
Publication
Weinheim ,
Subject
Physics
Chemistry
Engineering sciences. Technology
Source (journal)
Small. - Weinheim
Volume/pages
10(2014) :19 , p. 3895-3900
ISSN
1613-6810
ISI
000344451900011
Carrier
E
Target language
English (eng)
Full text (Publishers DOI)
Affiliation
University of Antwerp
Abstract
Thumbnail image of graphical abstract It is well known that metals with higher electron affinity like Au tend to undergo reduction rather than cation-exchange. It is experimentally shown that under certain conditions cation-exchange is dominant over reduction. Thermodynamic calculation further consolidates the understanding and paves the way for better predictability of cation-exchange/reduction reactions for other systems.
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