Publication
Title
Chemoselective addition of isocyanides to N-tert-butanesulfinimines
Author
Abstract
The reaction of isocyanides with N-tert-butanesulfinimines shows remarkable chemoselectivity. β-Sulfinylamino isocyanides are formed exclusively with aromatic sulfinimines, while α-sulfeneimino acetamides result when using aliphatic derivatives. A mechanism is suggested for the latter transformation, together with an explanation for the observed selectivity. Finally, a scope study is presented for this remarkably chemoselective reaction.
Language
English
Source (journal)
Organic letters / American Chemical Society. - Washington, D.C.
Publication
Washington, D.C. : 2014
ISSN
1523-7060
Volume/pages
16:19(2014), p. 5116-5119
ISI
000342719500038
Full text (Publisher's DOI)
Full text (open access)
UAntwerpen
Faculty/Department
Research group
Publication type
Subject
Affiliation
Publications with a UAntwerp address
External links
Web of Science
Record
Identification
Creation 22.10.2014
Last edited 04.05.2017
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