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Title
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Chemoselective addition of isocyanides to N-tert-butanesulfinimines
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Author
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Abstract
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| The reaction of isocyanides with N-tert-butanesulfinimines shows remarkable chemoselectivity. β-Sulfinylamino isocyanides are formed exclusively with aromatic sulfinimines, while α-sulfeneimino acetamides result when using aliphatic derivatives. A mechanism is suggested for the latter transformation, together with an explanation for the observed selectivity. Finally, a scope study is presented for this remarkably chemoselective reaction. |
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Language
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English
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Source (journal)
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Organic letters / American Chemical Society. - Washington, D.C.
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Publication
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Washington, D.C.
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2014
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ISSN
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1523-7060
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DOI
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10.1021/OL502463S
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Volume/pages
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16
:19
(2014)
, p. 5116-5119
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ISI
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000342719500038
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Full text (Publisher's DOI)
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Full text (open access)
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