Title
Consistent analysis of the <tex>$Tl^{+}_{2}$</tex> and <tex>$Pb^{3+}_{2}$</tex> centers ESR parametersConsistent analysis of the <tex>$Tl^{+}_{2}$</tex> and <tex>$Pb^{3+}_{2}$</tex> centers ESR parameters
Author
Faculty/Department
Faculty of Sciences. Physics
Research group
Department of Physics
Publication type
article
Publication
Berlin,
Subject
Physics
Source (journal)
Physica status solidi: B: basic research. - Berlin
Volume/pages
190(1995):2, p. 339-346
ISSN
0370-1972
ISI
A1995RQ21300001
Carrier
E
Target language
English (eng)
Full text (Publishers DOI)
Affiliation
University of Antwerp
Abstract
The electron spin resonance parameters of the Tl-2(+) and Pb-2(3+) dimer centers produced by electron trapping at pairs of neighboring Tl+ or Pb2+ impurity ions in alkali chlorides are reanalyzed. The analysis which uses a consistent set of molecular parameters is based on the molecular model previously employed to describe the ESR properties ol the homonuclear V-k self-trapped hole center, which has a complementary electronic configuration. In a rough approximation the analysis is extended to the self-trapped electron (STEL) center in PbCl2 crystals, which is a bent Pb-2(3+) molecular ion in a low symmetry crystal field.
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