Title
Adsorption and desorption in confined geometries : a discrete hopping model Adsorption and desorption in confined geometries : a discrete hopping model
Author
Faculty/Department
Faculty of Sciences. Physics
Publication type
article
Publication
Subject
Physics
Source (journal)
The European physical journal. Special topics
Volume/pages
223(2014) :14 , p. 3243-3256
ISSN
1951-6355
ISI
000346416400015
Carrier
E
Target language
English (eng)
Full text (Publishers DOI)
Affiliation
University of Antwerp
Abstract
We study the adsorption and desorption kinetics of interacting particles moving on a one-dimensional lattice. Confinement is introduced by limiting the number of particles on a lattice site. Adsorption and desorption are found to proceed at different rates, and are strongly influenced by the concentration-dependent transport diffusion. Analytical solutions for the transport and self-diffusion are given for systems of length 1 and 2 and for a zero-range process. In the last situation the self- and transport diffusion can be calculated analytically for any length.
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Full text (open access)
https://repository.uantwerpen.be/docman/irua/ea2843/122779.pdf
Handle