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Title
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Adsorption and desorption in confined geometries : a discrete hopping model
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Author
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Abstract
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| We study the adsorption and desorption kinetics of interacting particles moving on a one-dimensional lattice. Confinement is introduced by limiting the number of particles on a lattice site. Adsorption and desorption are found to proceed at different rates, and are strongly influenced by the concentration-dependent transport diffusion. Analytical solutions for the transport and self-diffusion are given for systems of length 1 and 2 and for a zero-range process. In the last situation the self- and transport diffusion can be calculated analytically for any length. |
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Language
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English
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Source (journal)
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The European physical journal. Special topics. - -
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Publication
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2014
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ISSN
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1951-6355
[print]
1951-6401
[online]
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DOI
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10.1140/EPJST/E2014-02330-8
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Volume/pages
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223
:14
(2014)
, p. 3243-3256
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ISI
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000346416400015
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Full text (Publisher's DOI)
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Full text (open access)
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