Title
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N lone-pair interaction : a rotational study of chlorotrifluoroethylene ammonia
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Author
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Abstract
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The rotational spectra of four isotopologues of the adduct C2F3Cl-NH3 show that NH3 is bound to the partner molecule through a (N)lone-pair . . .pi interaction. Ammonia is located in proximity to the C2 atom (the one linked to two fluorine atoms), with the C2 . . .N distance = 2.987(2) angstrom. The nuclear hyperfine structure due to the quadrupole coupling effects of Cl-35/Cl-37 and N-14 nuclei has been fully resolved. The N-14 quadrupole coupling constants allow estimating the effective orientation of NH3 in the complex. |
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Language
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English
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Source (journal)
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Physical chemistry, chemical physics / Royal Society of Chemistry [London] - Cambridge, 1999, currens
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Publication
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Cambridge
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The Royal Society of Chemistry
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2015
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ISSN
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1463-9076
[print]
1463-9084
[online]
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DOI
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10.1039/C4CP05167J
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Volume/pages
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17
:12
(2015)
, p. 7694-7698
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ISI
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000351437500013
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Pubmed ID
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25484247
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Full text (Publisher's DOI)
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Full text (open access)
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