Publication
Title
N lone-pair interaction : a rotational study of chlorotrifluoroethylene ammonia
Author
Abstract
The rotational spectra of four isotopologues of the adduct C2F3Cl-NH3 show that NH3 is bound to the partner molecule through a (N)lone-pair . . .pi interaction. Ammonia is located in proximity to the C2 atom (the one linked to two fluorine atoms), with the C2 . . .N distance = 2.987(2) angstrom. The nuclear hyperfine structure due to the quadrupole coupling effects of Cl-35/Cl-37 and N-14 nuclei has been fully resolved. The N-14 quadrupole coupling constants allow estimating the effective orientation of NH3 in the complex.
Language
English
Source (journal)
Physical chemistry, chemical physics / Royal Society of Chemistry [London] - Cambridge, 1999, currens
Publication
Cambridge : 2015
ISSN
1463-9076 [print]
1463-9084 [online]
Volume/pages
17:12(2015), p. 7694-7698
ISI
000351437500013
Full text (Publisher's DOI)
Full text (open access)
UAntwerpen
Faculty/Department
Research group
Publication type
Subject
Affiliation
Publications with a UAntwerp address
External links
Web of Science
Record
Identification
Creation 12.05.2015
Last edited 10.08.2017
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