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Title
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Cation exchange mediated elimination of the Fe-antisites in the hydrothermal synthesis of
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Author
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Abstract
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| In this work we elucidate the elimination of mechanism Fe-antisite defects in lithium iron phosphate (LiFePO4) during the hydrothermal synthesis. Compelling evidence of this effect is provided by combining Neutron Powder Diffraction (NPD), High Resolution (Scanning) Transmission Electron Microscopy (HR-(S)TEM), Electron Energy Loss Spectroscopy (EELS), X-Ray Photoelectron Spectroscopy (XPS) and calculations. We found: i) the first intermediate vivianite inevitably creates Fe-antisite defects in LiFePO4; ii) the removal of these antisite defects by cation exchange is assisted by a nanometer-thick amorphous layer, rich in Li, that enwraps the LiFePO4 crystals. |
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Language
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English
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Source (journal)
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Nano energy. - -
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Publication
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Amsterdam
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Elsevier science bv
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2015
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ISSN
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2211-2855
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DOI
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10.1016/J.NANOEN.2015.06.005
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Volume/pages
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16
(2015)
, p. 256-267
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ISI
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000364579300027
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Full text (Publisher's DOI)
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Full text (open access)
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Full text (publisher's version - intranet only)
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