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Title
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Probing the coordination environment of ions coordinated to nitrogen-containing Lewis bases
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Author
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Abstract
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| Multi-frequency continuous-wave and pulsed EPR techniques are employed to investigate the coordination of nitrogen-containing ligands to Ti3+-chloro complexes. Frozen solutions of TiCl3 and TiCl3(Py)(3) dissolved in nitrogen-containing solvents have been investigated together with the TiCl3(Py)(3) solid-state complex. For these different systems, the hyperfine and nuclear quadrupole data of Ti3+-bound N-14 nuclei are reported and discussed in the light of DFT computations, allowing for a detailed description of the microscopic structure of these systems. |
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Language
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English
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Source (journal)
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Physical chemistry, chemical physics / Royal Society of Chemistry [London] - Cambridge, 1999, currens
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Publication
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Cambridge
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The Royal Society of Chemistry
,
2015
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ISSN
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1463-9076
[print]
1463-9084
[online]
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DOI
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10.1039/C5CP03417E
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Volume/pages
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17
:32
(2015)
, p. 20853-20860
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ISI
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000359237800045
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Pubmed ID
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26214506
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Full text (Publisher's DOI)
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Full text (publisher's version - intranet only)
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