Publication
Title
Probing the coordination environment of ions coordinated to nitrogen-containing Lewis bases
Author
Abstract
Multi-frequency continuous-wave and pulsed EPR techniques are employed to investigate the coordination of nitrogen-containing ligands to Ti3+-chloro complexes. Frozen solutions of TiCl3 and TiCl3(Py)(3) dissolved in nitrogen-containing solvents have been investigated together with the TiCl3(Py)(3) solid-state complex. For these different systems, the hyperfine and nuclear quadrupole data of Ti3+-bound N-14 nuclei are reported and discussed in the light of DFT computations, allowing for a detailed description of the microscopic structure of these systems.
Language
English
Source (journal)
Physical chemistry, chemical physics / Royal Society of Chemistry [London] - Cambridge, 1999, currens
Publication
Cambridge : 2015
ISSN
1463-9076 [print]
1463-9084 [online]
Volume/pages
17:32(2015), p. 20853-20860
ISI
000359237800045
Full text (Publishers DOI)
Full text (publishers version - intranet only)
UAntwerpen
Faculty/Department
Research group
Publication type
Subject
Affiliation
Publications with a UAntwerp address
External links
Web of Science
Record
Identification
Creation 05.10.2015
Last edited 23.05.2017
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