Title
Probing the coordination environment of <tex>$Ti^{3+}$</tex> ions coordinated to nitrogen-containing Lewis bases Probing the coordination environment of <tex>$Ti^{3+}$</tex> ions coordinated to nitrogen-containing Lewis bases
Author
Faculty/Department
Faculty of Sciences. Physics
Publication type
article
Publication
Cambridge ,
Subject
Physics
Chemistry
Source (journal)
Physical chemistry, chemical physics / Chemical Society [London] - Cambridge, 1999, currens
Volume/pages
17(2015) :32 , p. 20853-20860
ISSN
1463-9076
ISI
000359237800045
Carrier
E
Target language
English (eng)
Full text (Publishers DOI)
Affiliation
University of Antwerp
Abstract
Multi-frequency continuous-wave and pulsed EPR techniques are employed to investigate the coordination of nitrogen-containing ligands to Ti3+-chloro complexes. Frozen solutions of TiCl3 and TiCl3(Py)(3) dissolved in nitrogen-containing solvents have been investigated together with the TiCl3(Py)(3) solid-state complex. For these different systems, the hyperfine and nuclear quadrupole data of Ti3+-bound N-14 nuclei are reported and discussed in the light of DFT computations, allowing for a detailed description of the microscopic structure of these systems.
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