Title
The dominant pathways for the conversion of methane into oxygenates and syngas in an atmospheric pressure dielectric barrier discharge The dominant pathways for the conversion of methane into oxygenates and syngas in an atmospheric pressure dielectric barrier discharge
Author
Faculty/Department
Faculty of Sciences. Chemistry
Publication type
article
Publication
Washington, D.C. ,
Subject
Physics
Chemistry
Engineering sciences. Technology
Source (journal)
The journal of physical chemistry : C : nanomaterials and interfaces. - Washington, D.C., 2007, currens
Volume/pages
119(2015) :39 , p. 22331-22350
ISSN
1932-7447
ISI
000362385700010
Carrier
E
Target language
English (eng)
Full text (Publishers DOI)
Affiliation
University of Antwerp
Abstract
A one-dimensional fluid model for a dielectric barrier discharge in CH4/O-2 and CH4/CO2 gas mixtures is developed. The model describes the gas-phase chemistry for partial oxidation and for dry reforming of methane. The spatially averaged densities of the various plasma species are presented as a function of time and initial gas mixing ratio. Besides, the conversion of the inlet gases and the selectivities of the reaction products are calculated. Syngas, higher hydrocarbons, and higher oxygenates are typically found to be important reaction products. Furthermore, the main underlying reaction pathways for the formation of syngas, methanol, formaldehyde, and other higher oxygenates are determined.
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Full text (open access)
https://repository.uantwerpen.be/docman/irua/e60ef5/128774_2016_09_10.pdf
E-info
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