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Title
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Infrared and Raman-spectra of crystallization water in potassium N,N-dimethyloxathioamidate monohydrate
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Author
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Abstract
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| Raman and infrared measurements were performed on hydrated (H2O and D2O) and anhydrous (CH3)(2)NCSCOOK together with their CD3-substituted analogues. Close scrutiny of the water fundamentals indicated that the C-2v symmetry of the single water molecule is lost owing to different strengths of hydrogen bonding with the carboxylate and thioamide functional groups. The number of water fundamentals and the wavenumber and intensity changes at different temperatures are, considering the very complex structure of the water spectra, unexpectedly consistent with the predictions of a single asymmetric water molecule. |
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Language
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English
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Source (journal)
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Journal of Raman spectroscopy. - Dordrecht
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Publication
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Dordrecht
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1995
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ISSN
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0377-0486
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DOI
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10.1002/JRS.1250260112
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Volume/pages
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25
:1
(1995)
, p. 77-82
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ISI
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A1995QF62000010
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Full text (Publisher's DOI)
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