Title
Infrared and Raman-spectra of crystallization water in potassium N,N-dimethyloxathioamidate monohydrate
Author
Faculty/Department
Faculty of Sciences. Chemistry
Publication type
article
Publication
Dordrecht ,
Subject
Chemistry
Source (journal)
Journal of Raman spectroscopy. - Dordrecht
Volume/pages
25(1995) :1 , p. 77-82
ISSN
0377-0486
0377-0486
ISI
A1995QF62000010
Carrier
E
Target language
English (eng)
Full text (Publishers DOI)
Affiliation
University of Antwerp
Abstract
Raman and infrared measurements were performed on hydrated (H2O and D2O) and anhydrous (CH3)(2)NCSCOOK together with their CD3-substituted analogues. Close scrutiny of the water fundamentals indicated that the C-2v symmetry of the single water molecule is lost owing to different strengths of hydrogen bonding with the carboxylate and thioamide functional groups. The number of water fundamentals and the wavenumber and intensity changes at different temperatures are, considering the very complex structure of the water spectra, unexpectedly consistent with the predictions of a single asymmetric water molecule.
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