Publication
Title
Infrared and Raman-spectra of crystallization water in potassium N,N-dimethyloxathioamidate monohydrate
Author
Abstract
Raman and infrared measurements were performed on hydrated (H2O and D2O) and anhydrous (CH3)(2)NCSCOOK together with their CD3-substituted analogues. Close scrutiny of the water fundamentals indicated that the C-2v symmetry of the single water molecule is lost owing to different strengths of hydrogen bonding with the carboxylate and thioamide functional groups. The number of water fundamentals and the wavenumber and intensity changes at different temperatures are, considering the very complex structure of the water spectra, unexpectedly consistent with the predictions of a single asymmetric water molecule.
Language
English
Source (journal)
Journal of Raman spectroscopy. - Dordrecht
Publication
Dordrecht : 1995
ISSN
0377-0486
Volume/pages
25:1(1995), p. 77-82
ISI
A1995QF62000010
Full text (Publisher's DOI)
UAntwerpen
Faculty/Department
Research group
Publication type
Subject
Affiliation
Publications with a UAntwerp address
External links
Web of Science
Record
Identification
Creation 08.10.2008
Last edited 01.09.2017
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