Title
Spectroscopic study of cationic complexes of dithiomalonamide with Ni(II), Pd(II) and Pt(II) Spectroscopic study of cationic complexes of dithiomalonamide with Ni(II), Pd(II) and Pt(II)
Author
Faculty/Department
Faculty of Sciences. Chemistry
Publication type
article
Publication
Oxford ,
Subject
Chemistry
Source (journal)
Spectrochimica acta: part A: molecular spectroscopy. - Oxford, 1967 - 1994
Volume/pages
51(1995) :10 , p. 1617-1633
ISSN
0584-8539
ISI
A1995TD75700003
Carrier
E
Target language
English (eng)
Full text (Publishers DOI)
Affiliation
University of Antwerp
Abstract
In acid medium dithiomalonamide forms stable, cationic complexes of general formula: M(H(2)A)(2)X(2) (M is Ni(II), Pd(II), Pt(II); H(2)A is H2NCSCH2CSNH2; X is Cl, Br, I, ClO4). A full vibrational analysis (infrared and Raman spectroscopy) is presented and the influence of the central metal ion and the counterion is investigated. Furthermore some solid state exchange reactions are studied and the thermal behaviour of the complexes is described. Finally the compounds are compared with analogous complexes of dithiooxamide. It seems that the presence of the methylene function between the thioamide groups in dithiomalonamide creates a series of interesting features.
E-info
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