Publication
Title
Spectroscopic study of cationic complexes of dithiomalonamide with Ni(II), Pd(II) and Pt(II)
Author
Abstract
In acid medium dithiomalonamide forms stable, cationic complexes of general formula: M(H(2)A)(2)X(2) (M is Ni(II), Pd(II), Pt(II); H(2)A is H2NCSCH2CSNH2; X is Cl, Br, I, ClO4). A full vibrational analysis (infrared and Raman spectroscopy) is presented and the influence of the central metal ion and the counterion is investigated. Furthermore some solid state exchange reactions are studied and the thermal behaviour of the complexes is described. Finally the compounds are compared with analogous complexes of dithiooxamide. It seems that the presence of the methylene function between the thioamide groups in dithiomalonamide creates a series of interesting features.
Language
English
Source (journal)
Spectrochimica acta: part A: molecular spectroscopy. - Oxford, 1967 - 1994
Publication
Oxford : 1995
ISSN
0584-8539
Volume/pages
51:10(1995), p. 1617-1633
ISI
A1995TD75700003
Full text (Publisher's DOI)
Full text (publisher's version - intranet only)
UAntwerpen
Faculty/Department
Research group
Publication type
Subject
Affiliation
Publications with a UAntwerp address
External links
Web of Science
Record
Identification
Creation 08.10.2008
Last edited 19.07.2017
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