Publication
Title
Ligand-driven anion-π interaction-induced silver(I) coordination chemistry
Author
Abstract
Three novel coordination compounds were successfully isolated using rare and poorly studied 5-phenyl-2,2′-bipyridine (LI) and completely unexplored 6-phenyl-3-(pyridin-2-yl)-1,2,4-triazine (LII) ligands with AgNO3, namely, [Ag(LI)2]NO3·0.5H2O (1), [Ag(LI)PPh3NO3]·0.5CH2Cl2 (2), and [Ag2(LII)2(H2O)2](NO3)2 (3). 1 can be converted into 2 upon reacting with PPh3, while no conversion was observed for 3. The formation of 3 was templated through anion−π-system interactions between the NO3 anions and the electron deficient 1,2,4-triazine ring of LII, which play a crucial role in the supramolecular assembly.
Language
English
Source (journal)
Crystal growth & design
Publication
2016
ISSN
1528-7483
Volume/pages
16:7(2016), p. 3763-3770
ISI
000379456700027
Full text (Publisher's DOI)
Full text (open access)
UAntwerpen
Faculty/Department
Research group
Publication type
Subject
Affiliation
Publications with a UAntwerp address
External links
Web of Science
Record
Identification
Creation 07.06.2016
Last edited 26.11.2017
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