Iodide-catalyzed synthesis of secondary thiocarbamates from isocyanides and thiosulfonatesIodide-catalyzed synthesis of secondary thiocarbamates from isocyanides and thiosulfonates
Faculty of Sciences. Chemistry
Faculty of Sciences. Physics
Biophysics and Biomedical Physics
2016Washington, D.C., 2016
Organic letters / American Chemical Society. - Washington, D.C.
18(2016):12, p. 2808-2811
University of Antwerp
A new method for the synthesis of secondary thiocarbamates from readily available isocyanides and thiosulfonates with broad functional group tolerance is reported. The reaction proceeds under mild reaction conditions in isopropanol and is catalyzed by inexpensive sodium iodide.