Title
Iodide-catalyzed synthesis of secondary thiocarbamates from isocyanides and thiosulfonates Iodide-catalyzed synthesis of secondary thiocarbamates from isocyanides and thiosulfonates
Author
Faculty/Department
Faculty of Sciences. Chemistry
Faculty of Sciences. Physics
Publication type
article
Publication
Washington, D.C. ,
Subject
Physics
Chemistry
Source (journal)
Organic letters / American Chemical Society. - Washington, D.C.
Volume/pages
18(2016) :12 , p. 2808-2811
ISSN
1523-7060
Carrier
E
Target language
English (eng)
Full text (Publishers DOI)
Affiliation
University of Antwerp
Abstract
A new method for the synthesis of secondary thiocarbamates from readily available isocyanides and thiosulfonates with broad functional group tolerance is reported. The reaction proceeds under mild reaction conditions in isopropanol and is catalyzed by inexpensive sodium iodide.
E-info
https://repository.uantwerpen.be/docman/iruaauth/d9cbbe/133940.pdf
Handle