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Title
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The self-associating behavior of and in liquid xenon
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Author
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Abstract
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| In this study we report on the analysis of isothermal spectra of NH3 and ND3 solutions in liquid xenon at 203 K using newly developed and validated least-squares approaches to investigate the its self associating behavior. For both species we observe clear dimer bands in the spectral area of the v(1)+v(4), v(3)+v(4) and v(1)+v(2), v(3)+v(2) combination bands. The analysis of the N-D stretching area, allows us to characterize clear contributions of dimers and trimers. The analysis of the N-H stretching area is hampered by the occurrence of a time dependent band due to solid water traces during the experiments. For NH3 we also performed an investigation of the N-H bending region, v(2), which demonstrated a small dimer absorption band. These obtained results compare well with literature data. (C) 2016 Elsevier B.V. All rights reserved. |
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Language
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English
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Source (journal)
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Journal of molecular structure. - Amsterdam
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Publication
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Amsterdam
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2016
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ISSN
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0022-2860
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DOI
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10.1016/J.MOLSTRUC.2016.03.089
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Volume/pages
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1118
(2016)
, p. 34-41
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ISI
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000377828700005
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Full text (Publisher's DOI)
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Full text (open access)
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Full text (publisher's version - intranet only)
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