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Title
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Rotational study of dimethyl ether-chlorotrifluoroethylene : lone pair interaction links the two subunits
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Author
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Abstract
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| The rotational spectra of two isotopologues of chlorotrifluoroethylene-dimethyl ether show that the two constituent molecules are held together by a lone pair center dot center dot center dot pi interaction. The ether oxygen is linked to the (CF2) carbon atom, with a C-O distance of 2.908 angstrom. |
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Language
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English
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Source (journal)
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The journal of physical chemistry : A : molecules, spectroscopy, kinetics, environment and general theory. - Washington, D.C., 1997, currens
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Publication
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Washington, D.C.
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2016
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ISSN
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1089-5639
[print]
1520-5215
[online]
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DOI
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10.1021/ACS.JPCA.5B12571
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Volume/pages
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120
:27
(2016)
, p. 4939-4943
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ISI
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000379988900039
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Pubmed ID
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26812179
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Full text (Publisher's DOI)
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Full text (publisher's version - intranet only)
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