Publication
Title
Post-synthesis bromination of benzene bridged PMO as a way to create a high potential hybrid material
Author
Abstract
Periodic mesoporous organosilicas provide the best of two worlds: the strength and porosity of an inorganic framework combined with the infinite possibilities created by the organic bridging unit. In this work we focus on post-synthetical modification of benzene bridged PMO, in order to create bromobenzene PMO. In the past, this proved to be very challenging due to unwanted structural deterioration. However, now we have found a way to brominate this material whilst keeping the structure intact. In-depth structural analysis by solid state NMR and XPS shows both vast progress over previous attempts as well as potential for improvement.
Language
English
Source (journal)
Microporous and mesoporous materials: zeolites, clays, carbons and related materials. - Amsterdam
Publication
Amsterdam : 2016
ISSN
1387-1811
Volume/pages
236(2016), p. 244-249
ISI
000385899600028
Full text (Publisher's DOI)
Full text (open access)
Full text (publisher's version - intranet only)
UAntwerpen
Faculty/Department
Research group
Publication type
Subject
Affiliation
Publications with a UAntwerp address
External links
Web of Science
Record
Identification
Creation 16.09.2016
Last edited 21.07.2017
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