Title
Post-synthesis bromination of benzene bridged PMO as a way to create a high potential hybrid material Post-synthesis bromination of benzene bridged PMO as a way to create a high potential hybrid material
Author
Faculty/Department
Faculty of Sciences. Chemistry
Faculty of Sciences. Physics
Publication type
article
Publication
Amsterdam ,
Subject
Physics
Chemistry
Source (journal)
Microporous and mesoporous materials: zeolites, clays, carbons and related materials. - Amsterdam
Volume/pages
236(2016) , p. 244-249
ISSN
1387-1811
Carrier
E
Target language
English (eng)
Full text (Publishers DOI)
Affiliation
University of Antwerp
Abstract
Periodic mesoporous organosilicas provide the best of two worlds: the strength and porosity of an inorganic framework combined with the infinite possibilities created by the organic bridging unit. In this work we focus on post-synthetical modification of benzene bridged PMO, in order to create bromobenzene PMO. In the past, this proved to be very challenging due to unwanted structural deterioration. However, now we have found a way to brominate this material whilst keeping the structure intact. In-depth structural analysis by solid state NMR and XPS shows both vast progress over previous attempts as well as potential for improvement.
Full text (open access)
https://repository.uantwerpen.be/docman/irua/fe46aa/135274.pdf
E-info
https://repository.uantwerpen.be/docman/iruaauth/180fcd/135274.pdf
Handle