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Title
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Structural chemistry and magnetic properties of the perovskite
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Author
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Abstract
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| A polycrystalline sample of SrLa2Ni2TeO9 has been synthesized using a standard ceramic method and characterized by neutron diffraction, magnetometry and electron microscopy. The compound adopts a monoclinic, perovskite-like structure with space group P2(1)/n in and unit cell parameters a=5.6008(1), b = 5.5872(1), c=7.9018(2) angstrom, p=90.021(6)degrees at room temperature. The two crystallographically-distinct B sites are occupied by Ni2+ and Te6+ in ratios of 83:17 and 50:50. Both ac and dc magnetometry suggest that the compound is a spin glass below 35 K but the neutron diffraction data show that some regions of the sample are antiferromagnetic. Electron microscopy revealed twinning on a nanoscale and local variations in composition. These defects are thought to be responsible for the presence of two distinct types of antiferromagnetic ordering. (C) 2016 The Authors. Published by Elsevier Inc. |
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Language
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English
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Source (journal)
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Journal of solid state chemistry. - London
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Publication
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London
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2016
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ISSN
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0022-4596
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DOI
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10.1016/J.JSSC.2016.09.004
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Volume/pages
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243
(2016)
, p. 304-311
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ISI
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000384874100041
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Full text (Publisher's DOI)
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Full text (open access)
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