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Title
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Optical readout of controlled monomer-dimer self-assembly
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Author
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Abstract
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| 5,7-Substituted 1,4-diazepinoporphyrazine magnesium(II) complexes were synthesized via Mg(II)-alkoxide templated macrocyclization. A single crystal growth synchrotron diffraction analysis permitted what is to our knowledge the first structural characterization of a 1,4-diazepinoporphyrazine. It exists as a dimer in the solid state. In silico calculations supported by solution phase spectral studies involving a series of representative derivatives, provided insights into the factors governing dimerization of 1,4-diazepinoporphyrazines. The present 1,4-diazepinoporphyrazines serve as useful probes for understanding the determinants that guide dimermonomer equilibria and the self-assembly of phthalocyanine derivatives. |
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Language
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English
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Source (journal)
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Dalton Transactions : an international journal of inorganic chemistry / Royal Society of Chemistry [London] - Cambridge, 2003, currens
Journal of the Chemical Society : Dalton transactions. - London, 1972 - 1999
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Publication
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Cambridge
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Royal Society of Chemistry
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2018
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ISSN
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1477-9226
[print]
1477-9234
[online]
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DOI
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10.1039/C8DT00384J
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Volume/pages
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47
:40
(2018)
, p. 14169-14173
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ISI
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000447708900005
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Pubmed ID
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29664072
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Full text (Publisher's DOI)
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Full text (open access)
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