Publication
Title
Optical readout of controlled monomer-dimer self-assembly
Author
Abstract
5,7-Substituted 1,4-diazepinoporphyrazine magnesium(II) complexes were synthesized via Mg(II)-alkoxide templated macrocyclization. A single crystal growth synchrotron diffraction analysis permitted what is to our knowledge the first structural characterization of a 1,4-diazepinoporphyrazine. It exists as a dimer in the solid state. In silico calculations supported by solution phase spectral studies involving a series of representative derivatives, provided insights into the factors governing dimerization of 1,4-diazepinoporphyrazines. The present 1,4-diazepinoporphyrazines serve as useful probes for understanding the determinants that guide dimermonomer equilibria and the self-assembly of phthalocyanine derivatives.
Language
English
Source (journal)
Journal of the Chemical Society: Dalton transactions. - London
Journal of the Chemical Society: Dalton transactions. - London
Publication
London : 2018
ISSN
0300-9246
1477-9226
1472-7773
Volume/pages
47 :40 (2018) , p. 14169-14173
ISI
000447708900005
Pubmed ID
29664072
Full text (Publisher's DOI)
Full text (open access)
UAntwerpen
Faculty/Department
Research group
Publication type
Subject
Affiliation
Publications with a UAntwerp address
External links
Web of Science
Record
Identification
Creation 24.05.2018
Last edited 29.11.2021
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