|
Title
|
|
|
|
Hierarchically dual-mesoporous microspheres for enhanced photocatalytic properties and lithium storage
| |
|
Author
|
|
|
|
| |
|
Abstract
|
|
|
|
| Hierarchically dual‐mesoporous TiO2 microspheres have been synthesized via a solvothermal process in the presence of 1‐butyl‐3‐methylmidazolium tetrafluoroborate ([BMIm][BF4]) and diethylenetriamine (DETA) as co‐templates. Secondary mesostructured defects in the hierarchical TiO2 microspheres produce the oxygen vacancies, which not only significantly enhance the photocatalytic activity on degrading methyl blue (over 1.7 times to P25) and acetone (over 2.9 times of P25), but which also are beneficial for lithium storage. Moreover, we propose a mechanism to obtain a better understanding of the role of dual mesoporosity of TiO2 microspheres for enhancing the molecular diffusion, ion transportation and electron transformation. |
| |
|
Language
|
|
|
|
English
| |
|
Source (journal)
|
|
|
|
Chemistry: a European journal. - Weinheim
| |
|
Publication
|
|
|
|
Weinheim
:
2018
| |
|
ISSN
|
|
|
|
0947-6539
| |
|
DOI
|
|
|
|
10.1002/CHEM.201801933
| |
|
Volume/pages
|
|
|
|
24
:50
(2018)
, p. 13246-13252
| |
|
ISI
|
|
|
|
000443804100025
| |
|
Pubmed ID
|
|
|
|
29926980
| |
|
Full text (Publisher's DOI)
|
|
|
|
| |
|
Full text (open access)
|
|
|
|
| |
|
Full text (publisher's version - intranet only)
|
|
|
|
| |
|