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Title
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Ferrimagnetism as a consequence of unusual cation ordering in the Perovskite
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Author
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Abstract
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| A polycrystalline sample of SrLa2FeCoSbO9 has been prepared in a solid-state reaction and studied by a combination of electron microscopy, magnetometry, Mossbauer spectroscopy, X-ray diffraction, and neutron diffraction. The compound adopts a monoclinic (space group P2(1)/n; a = 5.6218(6), b = 5.6221(6), c = 7.9440(8) angstrom, beta = 90.050(7)degrees at 300 K) perovskite-like crystal structure with two crystallographically distinct six-coordinate sites. One of these sites is occupied by 2/3 Co-2(+),1/3 Fe3+ and the other by 2/3 Sb5+, 1/3 Fe3+. This pattern of cation ordering results in a transition to a ferrimagnetic phase at 215 K. The magnetic moments on nearest-neighbor, six-coordinate cations align in an antiparallel manner, and the presence of diamagnetic Sb5+ on only one of the two sites results in a nonzero remanent magnetization of similar to 1 mu(B) per formula unit at 5 K. |
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Language
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English
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Source (journal)
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Inorganic chemistry / American Chemical Society. - Easton, Pa
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Publication
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Easton, Pa
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2018
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ISSN
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0020-1669
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DOI
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10.1021/ACS.INORGCHEM.8B01012
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Volume/pages
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57
:12
(2018)
, p. 7438-7445
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ISI
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000436023800073
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Pubmed ID
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29808998
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Full text (Publisher's DOI)
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Full text (publisher's version - intranet only)
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