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Title
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Incommensurately modulated structures and luminescence properties of the (x=0.286, 0.2) scheelites as thermographic phosphors
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Author
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Abstract
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| Ag+ for Sm3+ substitution in the scheelite-type AgxSm(2-x)/3 square(1-2x)/3WO4 tungstates has been investigated for its influence on the cation-vacancy ordering and luminescence properties. A solid state method was used to synthesize the x = 0.286 and x = 0.2 compounds, which exhibited (3 + 1)D incommensurately modulated structures in the transmission electron microscopy study. Their structures were refined using high resolution synchrotron powder X-ray diffraction data. Under near-ultraviolet light, both compounds show the characteristic emission lines for (4)G(5/2) -> H-6(J) (J = 5/2, 7/2, 9/2, and 11/2) transitions of the Sm3+ ions in the range 550-720 nm, with the J = 9/2 transition at the similar to 648 nm region being dominant for all photoluminescence spectra. The intensities of the (4)G(5/2) -> H-6(9/2) and (4)G(5/2) -> H-6(7/2) bands have different temperature dependencies. The emission intensity ratios (R) for these bands vary reproducibly with temperature, allowing the use of these materials as thermographic phosphors. |
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Language
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English
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Source (journal)
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Chemistry of materials / American Chemical Society. - Washington, D.C., 1989, currens
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Publication
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Washington, D.C.
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2018
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ISSN
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0897-4756
[print]
1520-5002
[online]
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DOI
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10.1021/ACS.CHEMMATER.8B02029
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Volume/pages
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30
:14
(2018)
, p. 4788-4798
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ISI
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000440105500037
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Full text (Publisher's DOI)
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Full text (publisher's version - intranet only)
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