Publication
Title
A continuous in-situ EPR electrochemical reactor as a rapid in-depth mechanistic screening tool for electrocatalysis
Author
Abstract
In this work, an improved in-situ EPR hydrodynamic electrochemical cell design is constructed and validated. The created platform enables the fast and accurate screening of new electrocatalytic materials, providing insights into their effects on radical products of a reaction. Furthermore, it is essential that the reaction kinetics are not influenced by the set-up and that mass transfer can be controlled. Our modular design allows for fast and easy replacement of parts and adjustments to electrodes in order to unravel the catalysts' influence on radical formation. The proximity of the pseudo-reference electrode to the working electrode in combination with the flow and electrode positioning allows for good potential control. The POM housing allows easy manipulation of the channel and excludes the use of sealing agents.
Language
English
Source (journal)
Electrochemistry communications. - Amsterdam
Related dataset(s)
Publication
Amsterdam : 2018
ISSN
1388-2481
1873-1902
DOI
10.1016/J.ELECOM.2018.10.010
Volume/pages
97 (2018) , p. 42-45
ISI
000451326800009
Full text (Publisher's DOI)
Full text (open access)
Full text (publisher's version - intranet only)
UAntwerpen
Faculty/Department
Research group
Project info
Immobilized proteins in porous materials - Structural studies by Pulse EPR dipolar spectroscopY (iSPY).
Towards a targeted optimization of electrocatalysts by combining electrosynthesis with in-situ electron paramagnetic resonance.
Advanced support materials for electrocatalysis
Publication type
Subject
Affiliation
Publications with a UAntwerp address
External links
Web of Science
Record
Identifier
Creation 15.10.2018
Last edited 02.10.2024
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