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Title
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Lewis acidic promoted 2-aza-Cope rearrangement to afford alpha-substituted homoallylamines in dimethyl carbonate
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Author
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Abstract
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| The iron(iii)-catalyzed efficient strategy for the synthesis of alpha-substituted homoallylamines was accomplished via a cationic 2-aza-Cope rearrangement of aldimines, generated in situ by condensation of commercially available aldehydes and easily synthesizable 1,1-diphenylhomoallylamines. This reaction features a broad substrate scope with high yields and is conducted in an eco-friendly solvent, i.e. dimethyl carbonate. |
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Language
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English
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Source (journal)
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RSC advances
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Publication
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2019
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ISSN
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2046-2069
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DOI
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10.1039/C9RA03277K
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Volume/pages
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9
:31
(2019)
, p. 18013-18017
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ISI
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000471914300058
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Full text (Publisher's DOI)
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Full text (open access)
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