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Title
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Thiazolium carbene catalysts for the fixation of onto amines
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Author
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Abstract
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| The catalytic N-formylation and N-methylation of amines using CO2 as the carbon source represents a facile and sustainable approach for the synthesis of pharmaceuticals and natural products. Herein, we describe highly effective and inexpensive thiazolium carbene-based catalysts derived from vitamin B1 for the N-formylation and N-methylation of amines, using polymethylhydrosiloxane (PMHS) as a reducing agent, which operate under ambient conditions. |
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Language
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English
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Source (journal)
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Chemical communications / Royal Society of Chemistry [London] - London, 1996, currens
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Publication
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London
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Royal Society of Chemistry
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2016
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ISSN
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1359-7345
[print]
1364-548X
[online]
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DOI
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10.1039/C5CC08741D
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Volume/pages
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52
:12
(2016)
, p. 2497-2500
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ISI
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000369589000011
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Full text (Publisher's DOI)
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