Publication
Title
Misfit accommodation in oxide thin film heterostructures
Author
Abstract
Complex oxides are of intense interest due to their diverse properties, such as colossal magnetoresistance and superconductivity. Their complexity arises not only from the number of constituent elements, but also from their tolerance of non-stoichiometry and the structural complexity of these perovskite-based materials, e.g. the distortions and rotations of the oxygen octahedra surrounding the B-site cation. For these reasons, misfit accommodation in these materials is far more complex than in simpler materials, and can involve several different mechanisms simultaneously. In some cases, interfaces can be free from any misfit dislocations, lattice mismatch being accommodated via incorporation of oxygen vacancies, which take an ordered periodic arrangement. Interfaces may also present a perturbation to the octahedral rotations that can dramatically affect properties, not just close to the interface but through the entire film. In oxygen ion conducting materials, the oxygen sublattice may even melt in some situations. (c) 2012 Acta Materialia Inc. Published by Elsevier Ltd. All rights reserved.
Language
English
Source (journal)
Acta materialia. - Oxford
Publication
Oxford : 2013
ISSN
1359-6454
DOI
10.1016/J.ACTAMAT.2012.09.069
Volume/pages
61 :8 (2013) , p. 2725-2733
ISI
000317797700002
Full text (Publisher's DOI)
UAntwerpen
Publication type
Subject
External links
Web of Science
Record
Identifier
Creation 17.02.2020
Last edited 09.12.2024
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