|
Title
|
|
|
|
Chemistry reduction of complex CO₂ chemical kinetics : application to a gliding arc plasma
| |
|
Author
|
|
|
|
| |
|
Abstract
|
|
|
|
| A gliding arc (GA) plasma has great potential for CO2 conversion into value-added chemicals, because of its high energy efficiency. To improve the application, a 2D/3D fluid model is needed to investigate the CO2 conversion mechanisms in the actual discharge geometry. Therefore, the complex CO2 chemical kinetics description must be reduced due to the huge computational cost associated with 2D/3D models. This paper presents a chemistry reduction method for CO2 plasmas, based on the so-called directed relation graph method. Depending on the defined threshold values, some marginal species are identified. By means of a sensitivity analysis, we can further reduce the chemistry set by removing one by one the marginal species. Based on the so-called flux-sensitivity coupling, we obtain a reduced CO2 kinetics model, consisting of 36 or 15 species (depending on whether the 21 asymmetric mode vibrational states of CO2 are explicitly included or lumped into one group), which is applied to a GA discharge. The results are compared with those predicted with the full chemistry set, and very good agreement is reached. Moreover, the range of validity of the reduced CO2 chemistry set is checked, telling us that this reduced set is suitable for low power GA discharges. Finally, the time and spatial evolution of the CO2 plasma characteristics are presented, based on a 2D model with the reduced kinetics. |
| |
|
Language
|
|
|
|
English
| |
|
Source (journal)
|
|
|
|
Plasma sources science and technology / Institute of Physics [Londen] - Bristol, 1992, currens
| |
|
Publication
|
|
|
|
Bristol
:
Institute of Physics
,
2020
| |
|
ISSN
|
|
|
|
0963-0252
| |
|
DOI
|
|
|
|
10.1088/1361-6595/AB540F
| |
|
Volume/pages
|
|
|
|
29
:2
(2020)
, p. 1-17
| |
|
Article Reference
|
|
|
|
025012
| |
|
ISI
|
|
|
|
000525600600001
| |
|
Medium
|
|
|
|
E-only publicatie
| |
|
Full text (Publisher's DOI)
|
|
|
|
| |
|
Full text (open access)
|
|
|
|
| |
|
Full text (publisher's version - intranet only)
|
|
|
|
| |
|