Title
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Utilising the principles of FeCO₃ scaling for cementation in H₂O-CO₂(g)-Fe system
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Author
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Abstract
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FeCO3 scaling is utilised in a system of closely packed wet Fe-particles (10 mu m) to prepare blocks composed of unreacted Fe-cores connected by a 'cementing matrix of FeCO3 scales'. Within four hours of carbonation at different temperatures (30 degrees C - 90 degrees C) and CO2-pressures (1 barg-20 barg), a compressive strength of up to 160 MPa, and a siderite (FeCO3) content of up to 28 % is observed. Typical rhombohedral and atypical needle-shaped FeCO3 crystal morphologies are observed. The dependence of phase composition/morphologies on reaction conditions/processes is discussed. This study is proposed as a prelude towards utilisation of Fe-rich industrial wastes for cementation. |
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Language
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English
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Source (journal)
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Corrosion science. - Oxford
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Publication
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Oxford
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2020
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ISSN
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0010-938X
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DOI
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10.1016/J.CORSCI.2020.108613
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Volume/pages
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169
(2020)
, p. 1-7
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Article Reference
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108613
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ISI
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000530031900017
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Medium
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E-only publicatie
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Full text (Publisher's DOI)
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Full text (publisher's version - intranet only)
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