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Title
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Rhenium tricarbonyl complexes with arenethiolate axial ligands
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Author
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Abstract
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| Due to their unique electronic and photophysical properties, rhenium(I) fac-tricarbonyl complexes of general formula [Re(NN)(CO)3X]n+ have been arousing constant interest in many diverse fields and applications, such as CO2 (photo)electroreduction, organic light emitting diodes and materials, sensors, biological applications and bio-imaging. The photophysical properties of [Re(NN)(CO)3X]n+ complexes can be modulated by structural variations of the ligands. Modifications of the NN diimine ligand and of the axial X ligand have been deeply investigated. However, thiolate ligands have scarcely been used in the synthesis of rhenium tricarbonyl complexes. We describe the synthesis of a series of Pyta and Tapy-based Re(I) fac-tricarbonyl complexes with diversely para-substituted arenethiolates in the coordination sphere and report on the electrochemical, photophysical properties and DFT studies of such complexes. |
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Language
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English
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Source (journal)
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New journal of chemistry. - Montrouge
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Publication
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Montrouge
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2018
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ISSN
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1144-0546
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DOI
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10.1039/C8NJ01960F
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Volume/pages
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42
:14
(2018)
, p. 11312-11323
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ISI
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000438394800013
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Full text (Publisher's DOI)
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Full text (open access)
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